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Polyether ether ketone (PEEK) is a colourless organicthermoplasticpolymer in the polyaryletherketone (PAEK) family, used in engineering applications. It was originally introduced by Victrex PLC, then Imperial Chemical Industries (ICI) in the early 1980s.^[2]

Synthesis[edit]

PEEK polymers are obtained by step-growth polymerization by the dialkylation of bisphenolate salts. Typical is the reaction of 4,4'-difluorobenzophenone with the disodium salt of hydroquinone, which is generated in situ by deprotonation with sodium carbonate. The reaction is conducted around 300 °C in polar aprotic solvents - such as diphenyl sulphone.^[3][4]

Properties[edit]

PEEK is a semicrystalline thermoplastic with excellent mechanical and chemical resistance properties that are retained to high temperatures. The processing conditions used to mold PEEK can influence the crystallinity and hence the mechanical properties. Its Young's modulus is 3.6 GPa and its tensile strength is 90 to 100 MPa.^[5] PEEK has a glass transition temperature of around 143 °C (289 °F) and melts around 343 °C (662 °F). Some grades have a useful operating temperature of up to 250 °C (482 °F)^{[citation needed]}. The thermal conductivity increases nearly linearly with temperature between room temperature and solidus temperature.^[6] It is highly resistant to thermal degradation,^[7] as well as to attack by both organic and aqueous environments. It is attacked by halogens and strong Brønsted and Lewis acids, as well as some halogenated compounds and aliphatic hydrocarbons at high temperatures. It is soluble in concentrated sulfuric acid at room temperature, although dissolution can take a very long time unless the polymer is in a form with a high surface-area-to-volume ratio, such as a fine powder or thin film. It has high resistance to biodegradation.

Applications[edit]

Because of its robustness, PEEK is used to fabricate items used in demanding applications, including bearings, piston parts, pumps, High-performance liquid chromatography columns, compressor plate valves, and electrical cableinsulation. It is one of the few plastics compatible with ultra-high vacuum applications. PEEK is considered an advanced biomaterial used in medical implants, e.g., use with a high-resolution magnetic resonance imaging (MRI), for creating a partial replacement skull in neurosurgical applications.

PEEK is finding increased use in spinal fusion devices and reinforcing rods. It is extensively used in the aerospace, automotive, and chemical process industries.^[8] PEEK seals and manifolds are commonly used in fluid applications. PEEK also performs well in applications where continuous high temperatures (up to 500 °F/260 °C) are common.^[9] Because of this and its low thermal conductivity, it is also used in FFF printing to thermally separate the hot end from the cold end.

I have tried using canvas.toDataUrl and canvas.toBlob to get an base64 encoded string of an image (screenshot). In both toDataUrl and toBlob, you can set the mime type as image/jpeg, image/png. Oct 06, 2010  Why? If you are going to treat any incoming data as if it was 'Some bytes that might represent something but we don't know what', then why not just ignore the content type you receive instead of trying to force the browser to claim it doesn't know what it is sending? Node.js application/octet-stream. @Wilt if the client wants to save it, then it doesn't matter what headers are sent (you can 'save' or 'save link as' on anything in your browser), as the headers are information, not rules so attachment could be considered 'best not to display this yourself' while inline as 'best to display this yourself if you can'. Either way, most browsers will use the filename value as the suggested name. Mar 13, 2018  Octet streams are quite simply larger sequences made up of 8 bit integers (AKA smaller 8 binary digit sequences). As you may have guessed, everything. Any general, binary format that the server doesn't recognize usually uses this MIME type. Upon receiving this type, most browsers prompt the user and give the user an option to save to disk.

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Processing options[edit]

PEEK melts at a relatively high temperature (343 °C / 649.4 °F) compared to most other thermoplastics. In the range of its melting temperature it can be processed using injection moulding or extrusion methods. It is technically feasible to process granular PEEK into filament form and 3D printing parts from the filament material using fused deposition modeling – FDM (or fused filament fabrication – FFF) technology.^[10][11]PEEK filaments have been demonstrated for producing medical devices up to class IIa.^[12] With this new filament, it is possible to use the FFF method for different medical applications like dentures.

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In its solid state PEEK is readily machinable, for example, by (CNC) milling machines and is commonly used to produce high-quality plastic parts that are thermostable and both electrically and thermally insulating. Filled grades of PEEK can also be CNC machined, but special care must be taken to properly manage stresses in the material.

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PEEK is considered a high-performance polymer, that is to say, its high price restricts its use to the most demanding applications only.

Shape-memory PEEK in biomechanical applications[edit]

PEEK is not traditionally a shape-memory polymer; however, recent advances in processing have allowed shape-memory behavior in PEEK with mechanical activation. This technology has expanded to applications in orthopedic surgery.^[13]

References[edit]

1. ^A. K. van der Vegt & L. E. Govaert, Polymeren, van keten tot kunstof, ISBN90-407-2388-5.
2. ^'Why PEEK?'. drakeplastics.com. Retrieved 23 April 2018.
3. ^David Parker; Jan Bussink; Hendrik T. van de Grampe; Gary W. Wheatley; Ernst-Ulrich Dorf; Edgar Ostlinning; Klaus Reinking (15 April 2012). Polymers, High-Temperature. Ullmann's Encyclopedia of Industrial Chemistry (online Version). doi:10.1002/14356007.a21_449.pub3. ISBN978-3527306732.(subscription required)
4. ^David Kemmish 'Update on the Technology and Applications of PolyArylEtherKetones' 2010. ISBN978-1-84735-408-2.
5. ^Material Properties Data: Polyetheretherketone (PEEK), www.makeitfrom.com.
6. ^J. Blumm, A. Lindemann, A. Schopper, 'Influence of the CNT content on the thermophysical properties of PEEK-CNT composites', Proceedings of the 29th Japan Symposium on Thermophysical Properties, October 8–10, 2008, Tokyo.
7. ^Patel, Parina; Hull, T. Richard; McCabe, Richard W.; Flath, Dianne; Grasmeder, John; Percy, Mike (May 2010). 'Mechanism of thermal decomposition of poly(ether ether ketone) (PEEK) from a review of decomposition studies'(PDF). Polymer Degradation and Stability. 95 (5): 709–718. doi:10.1016/j.polymdegradstab.2010.01.024.
8. ^Lauzon, Michael (May 4, 2012). 'Diversified Plastics Inc., PEEK playing role in space probe'. PlasticsNews.com. Crain Communications Inc. Retrieved May 6, 2012.
9. ^'Properties of PEEK Material'. www.uplandfab.com.
10. ^Newsom, Michael. 'Arevo Labs announces Carbon Fiber and Nanotube-reinforced High Performance materials for 3D Printing Process'. Solvay Press Releases. LouVan Communications Inc. Retrieved 27 January 2016.
11. ^Thryft, Ann. '3D Printing High-Strength Carbon Composites Using PEEK, PAEK'. Design News. Retrieved 27 January 2016.
12. ^Press release Indmatec PEEK MedTec.
13. ^Anonymous. 'Surgical Technologies; MedShape Solutions, Inc. Announces First FDA-cleared Shape Memory PEEK Device; Closing of $10M Equity Offering'. Medical Letter on the CDC & FDA.